Nitrogen heterocyclic carbene containing pentacoordinate iron dicarbonyl as a [Fe]-hydrogenase active site model.
نویسندگان
چکیده
A novel pentacoordinate mono iron dicarbonyl complex bearing a nitrogen heterocyclic carbene ligand was reported as a model of a [Fe]-hydrogenase active site, which exhibits interesting proton coupled CO binding reactivity, electro-catalytic proton reduction and catalytic transfer hydrogenation reactivity.
منابع مشابه
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ورودعنوان ژورنال:
- Dalton transactions
دوره 44 38 شماره
صفحات -
تاریخ انتشار 2015